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BATTERIES
We carry a competitive range of U.P.S.
and D.C. batteries.
U.P.S.
(uninterruptible power supply) sealed lead acid batteries are typically used
in fire alarm systems, exit signs, computers, data centers,
telecommunication equipment or other electrical equipment where an
unexpected power disruption could cause injuries, serious business
disruption and/or data loss. The primary role is to provide short-term
power when the input power source fails.
D.C. (deep cycle) batteries are
low-maintenance sealed lead-acid rechargeable batteries, typically
used in
power wheelchairs, electric bikes, mobility scooters and power golf caddies
and carts. They should be charged slowly - 8 to 12 hours and must always be
stored in a charged state. Leaving the battery in a discharged condition
causes sulfation, a condition that makes the battery difficult, if not
impossible, to recharge.
SPECIFICATIONS:
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Uninterrupted Power Source Batteries |
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Battery |
Width |
Depth |
Height * |
Weight |
Price |
Core Charge* |
Total |
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12V4.5AH |
90mm/ 3.5" |
69mm/ 2.75 |
100mm/ 4.0" |
1.6kg/ 3.5lbs |
30.00 |
1.00 |
31.00 |
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12V9AH |
151mm/ 6.0" |
63mm/ 2.5" |
100mm/ 4.0" |
2.73kg/ 6lbs |
40.00 |
2.00 |
42.00 |
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12V12AH |
151mm/ 6.0" |
98mm/ 3.9" |
100mm/ 4.0" |
4.32kg/ 9.5lbs |
50.00 |
4.00 |
54.00 |
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Deep Cycle
Batteries |
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12V14AH |
151mm/ 6.0" |
98mm/ 3.9" |
110mm/ 4.3" |
5.0kg/ 11lbs |
50.00 |
4.00 |
54.00 |
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12V20AH |
180mm/ 7.1" |
76mm/ 3.1" |
167mm/ 6.6" |
7.0kg/ 15.4lbs |
70.00 |
5.00 |
75.00 |
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12V28AH |
175mm/ 6.9" |
166mm/ 6.5" |
125mm/ 4.9" |
10.9kg/ 24lbs |
80.00 |
8.00 |
88.00 |
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12V33AH/
U-1
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196mm/ 7.7" |
135mm/ 5.3" |
162mm/ 6.4" |
11.2kg/ 25lbs |
110.00 |
10.00 |
120.00 |
12V38AH |
198mm/ 7.8" |
166mm/ 6.5" |
175mm/ 6.9" |
12kg/ 27lbs |
125.00 |
10.00 |
135.00 |
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12V55AH/ 22NF |
250mm/ 9.8" |
139mm/ 5.5" |
208mm/ 8.2" |
18.7kg/
41lbs |
155.00 |
10.00 |
165.00 |
12V75AH/ Grp 24 |
282mm/ 11.1" |
169mm/ 6.7" |
207mm/ 8.2" |
24.9kg/ 54.8lbs |
250.00 |
10.00 |
260.00 |
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12V100AH/
Grp 27 |
331mm/ 13" |
169mm/
6.7" |
207mm/
8.2" |
29.8kg/ 65.6lbs |
295.00 |
10.00 |
305.00 |
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* Height includes battery
terminals |
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* WHAT IS A CORE CHARGE?:
A core charge is a deposit you pay on new
batteries, until you return your old batteries. If you do not have the old
batteries with you at the time of your purchase, you must pay the core
charge. That charge is refunded to you when you return the old batteries.
Like a bottle deposit, the charge is designed to encourage recycling.
To receive a core charge refund, either exchange the old part at the time of
purchase; OR bring the old/original batteries, along with proof of payment
of the core charge in to Mobilityunlimited within 90 days of your purchase.
If the recyclable components of the batteries are intact, the core charge
will be returned. If they are not, then the customer will not receive a core
charge refund. |
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USING AND
PROLONGING THE LIFE OF YOUR BATTERY INVESTMENT |
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A common reason for motorized machines to
stop working or acting erratically is battery failure. Taking proper
care of them is very important. Mobility machine batteries are different
from car batteries. Deep cycle batteries are charged once a day and
supply large amounts of electricity while running. The life of a battery
depends on how heavily it is used. Batteries can last over 2 or 3 years
when properly maintained.
It is a misconception among owners of electric scooters, e-bikes,
golf machines and wheelchairs that batteries should be completely
discharged before recharging.
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SIX
EASY STEPS FOR MAINTAINING SEALED LEAD ACID BATTERIES |
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1. Avoid heavily discharging the
batteries.
2. Use the charger supplied with your machine and make sure, if
equipped, it is set to the proper battery type.
3. If you need to store your batteries for a period of time, it is best
to charge them at least every 8 weeks.
4. New batteries require conditioning for the first 5 to 10 charging
cycles to reach full power.
5. Do not use automotive battery chargers unless they have a setting for
Sealed Batteries.
6. Always charge batteries after use. |
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SEALED BATTERIES |
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Sealed batteries require no
maintenance other than keeping the terminals free of corrosion. Most
airlines only allow sealed batteries. These batteries are available
through MobilityUnlimited and other quality suppliers.
(MobilityUnlimited
Inc.....clean
green machines) |
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HOW LEAD ACID BATTERIES WORK
by Constantin von
Wentzel* |
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Here is a short run-through of
how lead-acid batteries work. Start with some basics and work your way
up - hence the absence of an alphabetical order. Depending on your
familiarity with the subject, you may want to scroll down more or less.
Voltage
Voltage is an
electrical measure which describes the potential to do work. The higher
the voltage, the greater its risk to you and your health. Systems that
use voltages below 50V are considered low-voltage and are not governed
by as strict (some might say arcane) set of rules as high-voltage
systems.
Current Current is
a measure of how many electrons are flowing through a conductor. Current
is usually measured in amperes (A). Current flow over time is defined as
ampere-hours (a.k.a. amp-hours or Ah), a product of the average current
and the amount of time it flowed.
Power
Power
is the product of voltage and current and is measured in Watts. Power
over time is usually defined in Watt-hours (Wh), the product of the
average number of watts and time. Your energy utility usually bills you
per kiloWatt-hour (kWh), which is 1,000 watt-hours.
What is a Lead-Acid Battery?
A lead-acid battery is a electrical storage device that uses a
reversible chemical reaction to store energy. It uses a combination of
lead plates or grids and an electrolyte consisting of a diluted sulphuric acid to convert electrical energy into potential chemical
energy and back again. The electrolyte of lead-acid batteries is
hazardous to your health and may produce burns and other permanent
damage if you come into contact with it. Thus, when dealing with
electrolyte protect yourself appropriately!
Deep Cycle vs. Starter Batteries
Batteries are typically built for specific purposes and
they differ in construction accordingly.
Broadly speaking, there are two
applications that manufacturers build their batteries for: Starting and Deep Cycle.
As the name implies,
Starter
Batteries are meant to get combustion
engines going. They have many thin lead plates which allow them to
discharge a lot of energy very quickly for a short amount of time.
However, they do not tolerate being discharged deeply, as the thin
lead plates needed for starter currents degrade quickly under deep
discharge and re-charging cycles. Most starter batteries will only
tolerate being completely discharged a few times before being
irreversibly damaged.
Deep Cycle
batteries have
thicker lead plates that make them tolerate deep discharges better.
They cannot dispense charge as quickly as a starter battery but can
also be used to start combustion engines. You would simply need a
bigger deep-cycle battery than if you had used a dedicated starter
type battery instead. The thicker the lead plates, the longer the life
span, all things being equal. Battery weight is a simple indicator for
the thickness of the lead plates used in a battery. The heavier a
battery for a given group size, the thicker the plates, and the better
the battery will tolerate deep discharges.
Some "Marine" batteries are sold as
dual-purpose batteries for starter and deep cycle applications.
However, the thin plates required for starting purposes inherently
compromise deep-cycle performance. Thus, such batteries should not be
cycled deeply and should be avoided for deep-cycle applications unless
space/weight constraints dictate otherwise.
Regular versus Valve-Regulated Lead Acid (VRLA) Batteries
Battery Containers come in several different configurations. Flooded
Batteries can be either the sealed or open variety.
Sealed Flooded Cells
are frequently found as starter batteries in cars. Their electrolyte
cannot be replenished. When enough electrolyte has evaporated due to
charging, age, or just ambient heat, the battery has to be replaced.
Deep-Cycle Flooded
cells usually have removable caps that allow you to replace any
electrolyte that has evaporated over time. Take care not to
contaminate the electrolyte - wipe the exterior container while
rinsing the towel frequently.
VRLA batteries remain
under constant pressure of 1-4 psi. This pressure helps the
recombination process under which 99+% of the Hydrogen and Oxygen
generated during charging are turned back into water. The two most
common VRLA batteries used today are the Gel and Absorbed Glass Mat (AGM)
variety.
Gel batteries feature
an electrolyte that has been immobilized using a gelling agent like
fumed silica.
AGM batteries feature
a thin fiberglass felt that holds the electrolyte in place like a
sponge.
Neither AGM or Gel cells will leak if inverted, pierced, etc. and
will continue to operate even under water.
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Battery Cells Battery Cells are the most
basic individual component of a battery. They consist of a container in
which the electrolyte and the lead plates can interact. Each lead-acid
cell fluctuates in voltage from about 2.12 Volts when full to about 1.75
volts when empty. Note the small voltage difference between a full and
an empty cell (another advantage of lead-acid batteries over rival
chemistries).
Battery Voltage
The nominal voltage of a lead-acid battery depends on the number of
cells that have been wired in series. As mentioned above, each battery
cell contributes a nominal voltage of 2 Volts, so a 12 Volt battery
usually consists of 6 cells wired in series.
State of Charge
The State of Charge describes how full a battery is. The exact voltage
to battery charge correlation is dependent on the temperature of the
battery. Cold batteries will show a lower voltage when full than hot
batteries. This is one of the reasons why quality alternator regulators
or high-powered charging systems use temperature probes on batteries.
Depth of Discharge (DOD)
The Depth of Discharge (DOD) is a measure of how deeply a battery is
discharged. When a battery is 100% full, then the DOD is 0%. Conversely,
when a battery is 100% empty, the DOD is 100%. The deeper batteries are
discharged on average, the shorter their so-called cycle life.
For example, starter batteries are not designed to be discharged deeply
(no more than 20% DOD). Indeed, if used as designed, they hardly
discharge at all: Engine starts are very energy-intensive but the
duration is very short. Most battery manufacturers advocate not
discharging their batteries more than 50% before re-charging them.
Battery Storage Capacity
The Amp-hour (Ah) Capacity of a battery tries to quantify the
amount of usable energy it can store at a nominal voltage. All things
equal, the greater the physical volume of a battery, the larger its
total storage capacity. Storage capacity is additive when batteries are
wired in parallel but not if they are wired in series.
Most marine, automotive, and RV applications use 12V DC. You have the
choice to either buy a 12V battery or to create a 12V system by wiring
several lower-voltage batteries/cells in Series. |
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When
two 6V, 100Ah batteries are wired in Series,
the voltage is
doubled but the amp-hour capacity remains 100Ah (Total Power =1200 Watt-hours).
You may decide to wire batteries in series because a single 12V
battery with the right storage capacity is simply too heavy, unwieldy,
or awkward to lift into place. Batteries consisting of fewer cells (and
hence lower voltage) in series can provide the same storage
capacity yet be portable. It is not unusual to see solar power
installations where the battery bank consists of a sea of 2V
batteries that have been wired in series. |
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Two 6V, 100Ah batteries wired in Parallel
will have a total storage capacity of 200Ah at 6V (or 1200
Watt-hours).
Battery banks consisting of 12V batteries wired in parallel are often seen on OEM
installations in boats and RVs
alike. Such banks are simple to wire up and require a minimum of
cabling. However, the wiring must have the
capacity to deal with a full battery bank.
You should fuse each battery individually in such a bank to ensure that
a battery gone bad will not affect the rest
of the bank. |
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Battery banks wired in Series-Parallel are even more complicated. Here,
four 6V cells are wired in two "strings" of 12VDC that were then wired
in parallel. Using 6V, 100Ah batteries, this system will have a storage
capacity of 200Ah at 12V or 2,400Wh.
Since such a system has more wiring, it is very important to group
'strings" logically and to label everything.
Furthermore, it is a very good idea to fuse every "string" of
series-wired batteries to ensure that a problem in one part of the
battery bank does not take the whole bank down.
We use Group GPL4C batteries exclusively on our boat. Since these
batteries have a nominal voltage of 6V, we have wired them in series for
the starter bank (2 batteries) and series-parallel for the house
bank (4 batteries).
Despite advances in instrumentation, the battery industry mostly
still advertises amp-hours as a capacity measure instead of watt-hours.
Hopefully, the battery and marine power instrumentation industry will
make a transition to Watt-hours (Wh) in the future.
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AVAILABLE CAPACITY vs. TOTAL
CAPACITY |
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Since batteries depend on a chemical reaction to produce electricity,
their Available Capacity depends in part on how quickly you attempt to
charge or discharge them relative to their Total Capacity. The Total
Capacity is frequently abbreviated to C and is a measure of how much
energy the battery can store. Available Capacity is always less than
Total Capacity.
Typically, the amp-hour capacity of a battery is measured at a rate of
discharge that will leave it empty in 20 hours (a.k.a. the C/20 rate).
If you attempt to discharge a battery faster than the C/20 rate, you
will have less available capacity and vice-versa. The more extreme the
deviation from the C/20 rate, the greater the available (as opposed to
total) capacity difference.
However, as you will discover in the next section, this effect is
non-linear. The available capacity at the C/100 rate (i.e. 100 hours to
discharge) is typically only 10% more than at the C/20 rate. Conversely,
a 10% reduction in available capacity is achieved just by going to a C/8
rate (on average). Thus, you are most likely to notice this effect with
engine starts and other high-current applications like inverters,
windlasses, desalination, or air conditioning systems.
For example, the starter in an engine will typically quickly outstrip
the capacity of the battery to keep cranking it for any length of time.
Hence the tip from mechanics to wait some time between engine start
attempts. Not only does it allow the engine starter to cool down, it
also allows the chemistry in the battery to "catch-up". As the battery
comes to a new equilibrium, its available capacity increases. A very
elegant equation developed in 1897 by a scientist called Peukert
describes the charging and discharging behavior of batteries.
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THE PEUKERT EFFECT |
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As you can see below, the Peukert equation consists of several
factors.
Peukerts Equation:
Iⁿ x T = C
where
· I
is the current (usually measured
in amperes)
· T
is time (usually measured in
hours)
· n
is the Peukert number / exponent
C
is the theoretical storage
capacity of the battery (usually measured in amp-hours). Use the C/100
capacity or add 10% to the storage capacity at the C/20 rate.
As you can see, the available current is dependent on the rate of
discharge and the Peukert exponent for the battery. The closer the
exponent is to 1 (one), the less the available capacity of a battery
will be affected by fast discharges. Peukerts numbers are derived
empirically and are usually available from manufacturers. They range
from about 2 for some flooded batteries down to 1.05 for some AGM cells.
The average peukerts exponent is 1.2 though the exact number depends on
the battery construction and chemistry.
The following image shows the dramatic impact of the Peukerts exponent
on the available capacity of a 120Ah battery, depending on the ampere
draw. As you can see, the lower the Peukerts Exponent, the lesser the
effect on available capacity. Note the dramatic difference in Available
Capacity between the average flooded cell (n = 1.20) and a deep cycle
AGM (n = 1.08) with high-current applications.

In the above picture, note how the low exponent battery (topmost curve)
has more than four times the available capacity over a high-exponent
battery (lowest curve). This chart uses a linear scale.
When the time comes to charge a battery, the Peukerts effect also comes
into play. The capacity of a battery to absorb a charge during the bulk
phase is also dependent on it's Peukerts number. This is one of the
reasons why AGM cells can be bulk charged at much higher rates than
either Gel or Flooded cells.
Reserve Minutes
Reserve Minutes are a measure of how long your battery can sustain a
load before it's available capacity has been completely used up. This
measure is especially useful for folks who want to run inverters,
fridges, and other large loads. The following chart has a logarithmic
time scale (minutes) - hence, the non-linear nature of the Peukert
effect is smoothed out quite a bit.

Note how batteries that have a high Peukerts Exponent will quickly run
out of capacity with high loads. Here, the low-exponent battery will
last over 100 minutes with a 50 ampere load, while the high-exponent
battery will last about 20 minutes. Thus, anytime you deal with large
loads relative to the battery capacity available, chose a low-exponent
battery. This is why many wheel-chairs and other electrically motorized
vehicles use AGMs.
This chart answers why starter batteries are built to have a low
Peukerts exponent. Otherwise, they'd simply not be able to crank an
engine for more than a few seconds. However, the thin plates that allow
flooded cells to work as starter batteries also make them too fragile
for deep-cycle use.
Conversion Efficiency
The conversion efficiency denotes how well a battery converts an
electrical charge into chemical energy and back again. The higher this
factor, the less energy is converted into heat and the faster a battery
can be charged without overheating (all other things being equal). The
lower the internal resistance of a battery, the better its conversion
efficiency.
One of the main reasons why lead-acid batteries dominate the energy
storage markets is that the conversion efficiency of lead-acid cells at
85%-95% is much higher than Nickel-Cadmium (a.k.a. NiCad) at 65%,
Alkaline (a.k.a. NiFe) at 60%, or other inexpensive battery technologies |
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BATTERY LIFE |
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Battery
manufacturers define the end-of-life of a battery when it can no longer
hold a proper charge (for example, a cell has shorted) or when the
available battery capacity is 80% or less than what the battery was
rated for. The life of Lead Acid batteries is usually limited by several
factors:
■ Cycle
Life
is a measure of how many charge and discharge cycles a battery can take
before its lead-plate grids/plates are expected to collapse and short
out. The greater the average depth-of-discharge, the shorter the cycle
life.
■ Age
also affects batteries as the chemistry inside them attacks the lead
plates. The healthier the "living conditions" of the batteries, the
longer they will serve you. Lead-Acid batteries like to be kept at a
full charge in a cool place. Only buy recently manufactured batteries,
so learn to decipher the date code stamped on every battery... (inquire
w/manufacturer). The longer the battery has sat in a store, the less
time it will serve you! Since lead-acid batteries will not freeze if
fully charged, you can store them in the cold during winter to maximize
their life.
■
Construction
has a big
role in battery life too, some designs are better at preserving
batteries than others and the suitability of a design for a given
application plays a role also. For example, flooded lead-acid cells will
typically fare worse than their VRLA brethren in operations that involve
a lot of jerky motion - the immobilized plates in VRLA cells will be
stressed less than suspended plates in cheap flooded cells.
■ Plate
Thickness
helps -
the thicker the plates, the more abuse, charge and discharge cycles they
can take. Thicker plates will also survive any equalization treatments
for sulphation better. The heavier
the battery for a given group size, the thicker the plates are, so you
can use weight as one guide to buying lead-acid batteries.
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Sulphation
is a constant threat to batteries that are not fully re-charged. A layer
of lead sulphate can form in these cells and
inhibit the electro-chemical reaction that allows you to
charge/discharge batteries. Many batteries can be saved from the
recycling heap if they are Equalized In closing, the design life
of a battery depends in part on its construction, its type, the
thickness of the plates, its charging
profiles, etc. All these factors come together to determine just how
long your battery may ultimately serve you.
Equalization
Sulphation layers form barrier coats on the lead plates in batteries
that inhibit their ability to store and dispense energy. The
equalization step is a last resort to break up the Sulphate layers using
a controlled overcharge. The process will cause the battery electrolyte
to boil and gas, so it should be only done under strict supervision and
with the proper precautions.
Gassing
Batteries start to gas when you attempt to charge them faster than they
can absorb the energy. The excess energy is turned into heat, which then
causes the electrolyte to boil and evaporate. The evaporated electrolyte
can be replenished in batteries with removable caps such as most flooded
deep-cycle batteries. Many car batteries are sealed and thus need to be
replaced when their electrolyte evaporates over time.
Since AGM and Gel cells are always sealed, it is very important to
guarantee they are not overcharged. The only way to ensure this is to
use a temperature-compensated charging system. Such chargers use a
temperature probe on the battery to ensure that the battery does not get
too hot. As the battery heats up, the charging current is reduced to
prevent thermal runaway, a very dangerous condition.
Thermal Runaway
This is a very dangerous condition that can occur if batteries are
charged too fast. One of the byproducts of Gassing are Oxygen and
Hydrogen. As the battery heats up, the gassing rate increases as well
and it becomes increasingly likely that the Hydrogen around it will
explode. The danger posed by high Hydrogen concentrations is one of the
reasons that the American Boat and
Yachting Council (ABYC)
requires that batteries be installed in
separate, well-ventilated areas.
Self-Discharge
The self-discharge rate is a measure of how much batteries discharge on
their own. The Self-Discharge rate is governed by the construction of
the battery and the metallurgy of the lead used inside.
For instance, flooded cells typically use lead alloyed with Antimony to
increase their mechanical strength. However, the Antimony also increases
the self-discharge rate to 8-40% per month. This is why flooded
lead-acid batteries should be in use often or left on a trickle-charger.
The lead found in Gel and AGM batteries does not require a lot of
mechanical strength since it is immobilized by the gel or fiberglass.
Thus, it is typically alloyed with Calcium to reduce Gassing and
Self-Discharge. The self-discharge of Gel and AGM batteries is only
2-10% per month and thus these batteries need less maintenance to keep
them happy.
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BATTERY GROUP SIZE |
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To further complicate matters, manufacturers for marine batteries make
them in all sorts of sizes and voltages. Battery case sizes are
typically denoted by a "Group Size" which has nothing to do with the
actual size of the battery. For example, Group 8D batteries are much
larger than Group 31 batteries. Here are some examples: |
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Table of Battery Group Sizes,
Voltages and Approximate Exterior Dimensions: |
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Battery Group |
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21 |
24 |
27 |
30H |
31 |
4D |
8D |
T105 |
GPL4C |
L16 |
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| Voltage |
12 |
12 |
12 |
12 |
12 |
12 |
12 |
6 |
6 |
6 |
Volts |
| Length |
8.19 |
10.25 |
12.06 |
13.5 |
13 |
20.75 |
20.75 |
10.38 |
10.35 |
11.62 |
Inches |
| Width |
6.81 |
6.81 |
6.81 |
6.81 |
6.72 |
8.75 |
10.95 |
7.13 |
7.06 |
7 |
Inches |
| Height |
8.75 |
8.87 |
9.25 |
9.25 |
9.44 |
9.88 |
10.17 |
11.2 |
11.57 |
17.56 |
Inches |
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Dimensions are approximate and vary
by manufacturer. Consult manufacturer data sheets for exact
dimension of container, location and type of terminals, etc. |
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The group size will merely indicate the approximate exterior dimensions
(including terminals) and voltage of the battery in question. However,
the exact dimensions can only be directly obtained from each
manufacturer.
Now that you are familiar with the lingo, click
HERE
for the differences between the various types of lead-acid batteries.
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MORE INFORMATION ABOUT
BATTERIES |
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Can the lead-acid battery compete in
modern times?
by Isidor Buchmann
The answer is YES. Lead-acid is the
oldest rechargeable battery in existence. It has retained a market share
in applications where newer battery chemistries would either be too
expensive or the upkeep would be too demanding. There are simply no
cost-effective alternatives for such applications as wheelchairs,
scooters, golf carts, people movers and UPS systems.
Invented by the French physician Gaston Planté in 1859, lead-acid was
the first rechargeable battery for commercial use. Today, the flooded
lead-acid battery holds a domineering position in automobiles, forklifts
and large uninterruptible power supply (UPS) systems.
During the mid 1970s, researchers developed a maintenance-free lead-acid
battery that could operate in any position. The liquid electrolyte was
transformed into moistened separators and the enclosure was sealed.
Safety valves were added to allow venting of gas during charge and
discharge.
Driven by different market needs, two lead-acid systems emerged: the
small sealed lead-acid (SLA), also known under the brand name of Gelcell,
and the large valve-regulated-lead-acid (VRLA). Technically, both
batteries are the same. (Engineers may argue that the word 'sealed lead
acid' is a misnomer because no rechargeable battery can be totally
sealed.)
Unlike the flooded lead acid battery, both SLA and VRLA are designed
with a low over-voltage potential to prohibit the battery from reaching
its gas-generating potential during charge. Excess charging would cause
gassing and water depletion. Consequently, these batteries can never be
charged to their full potential.
Finding the ideal charge voltage limit is critical. Any voltage level is
a compromise. A high voltage limit (above 2.40V/cell) produces good
battery performance but shortens the service life due to grid corrosion
on the positive plate. The corrosion is permanent. A low voltage (below
2.40V/cell) is safe if charged at a higher temperature but is subject to
sulfation on the negative plate.
Lead-acid is not subject to memory. Leaving the battery on float charge
for a prolonged time does not cause damage. The self-discharge is about
40% per year, one of the best on rechargeable batteries. In comparison,
nickel-cadmium self-discharges this amount in three months. Lead-acid is
relatively inexpensive to purchase but the operational costs can be more
expensive than the nickel-cadmium if full cycles are required on a
repetitive basis.
Lead-acid does not lend itself
to fast charging. Typical charge time is 8 to 16 hours. The battery must
always be stored in a charged state. Leaving the battery in a discharged
condition causes sulfation, a condition that makes the battery difficult, if
not impossible, to recharge.
Unlike nickel-cadmium, the lead-acid does not like deep cycling. A full
discharge causes extra strain and each cycle robs the battery of a small
amount of capacity. This wear-down characteristic also applies to other
battery chemistries in varying degrees. To prevent the battery from being
stressed through repetitive deep discharge, a larger battery is recommended.
Depending on the depth of discharge and operating temperature, the sealed
lead-acid provides 200 to 300 discharge/charge cycles. The primary reason
for its relatively short cycle life is grid corrosion of the positive
electrode, depletion of the active material and expansion of the positive
plates. These changes are most prevalent at higher operating temperatures.
Cycling does not prevent or reverse the trend.
The optimum operating temperature for the lead-acid battery is 25°C (77°F).
As a guideline, every 8°C (15°F) rise in temperature will cut the battery
life in half. VRLA, which would last for 10 years at 25°C (77°F), will only
be good for 5 years if operated at 33°C (95°F). Theoretically the same
battery would endure a little more than one year at a desert temperature of
42°C (107°F).
Among modern rechargeable batteries, the lead-acid battery family has the
lowest energy density, making it unsuitable for handheld devices that demand
compact size. In addition, performance at low temperatures is poor.
The sealed lead-acid battery is rated at a 5-hour discharge or 0.2C. Some
batteries are rated at a slow 20-hour discharge. Longer discharge times
produce higher capacity readings. The lead-acid performs well on high load
currents. During these pulses, discharge rates well in excess of 1C can be
drawn.
In terms of disposal, the lead-acid is less harmful than nickel-cadmium
but the high lead content and the electrolyte make the lead-acid
environmentally unfriendly.
Advantages
° Inexpensive and simple to
manufacture.
° Mature, reliable and well-understood technology - when used
correctly, lead-acid is durable and provides dependable service.
° The self-discharge is among the lowest of rechargeable battery
systems.
° Low maintenance requirements - no memory; no electrolyte to fill on
sealed version.
° Capable of high discharge rates.
Limitations
° Low energy density - poor weight-to-energy ratio limits use to
stationary and wheeled applications.
° Cannot be stored in a discharged condition - the cell voltage should
never drop below 2.10V.
° Allows only a limited number of full discharge cycles - well suited
for standby applications that require only occasional deep discharges.
° Lead content and electrolyte make the battery environmentally
unfriendly.
° Transportation restrictions on flooded lead acid - there are
environmental concerns regarding spillage.
° Thermal runaway can occur with
improper charging.
■ ■ ■
About the Author
Isidor Buchmann is the founder and CEO of Cadex Electronics Inc., in
Vancouver BC.
Mr. Buchmann has a background in radio communications and has studied
the behavior of rechargeable batteries in practical, everyday
applications for two decades. Award winning author of many articles and
books on batteries, Mr. Buchmann has delivered technical papers around
the world.
Cadex Electronics is a manufacturer of advanced battery chargers,
battery analyzers and PC software. For product information please visit
www.cadex.com.
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